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Basic IUPAC Organic Nomenclature

Polycyclic alkanes

There are three basic types of polycyclic systems based on how the rings are connected together.  There are slight differences in the way in which they are named.
The systems can be further classified according to the number of rings present (e.g.  2 = bicyclic, 3 = tricyclic, 4 = tetracyclic etc.)

(1) Spiro ring systems

Spiro ring systems share a single common atom.  Hence the rings join at a single "point" The simplest example is the C5 system shown to the right.

 

(2) Fused ring systems

Fused ring systems share two or more common atoms, hence the rings share one or more sides. 
The simplest polycyclic system is the C4 system shown to the right where the rings share two atoms (one common side).

 

(3) Bridged ring systems

If there are more than two common atoms then the a "bridged" system is obtained.
The simplest polycyclic system is the C4 system shown to the right where the rings contain three common atoms (two common sides). 

 

bridged ring system

 

 © Dr. Ian Hunt, Department of Chemistry, University of Calgary