ROESLER GROUP HOMEPAGE

synthetic inorganic and organometallic chemistry



List of publications


  1. R. Rösler, C. Silvestru, I. Haiduc, F. Kayser, M. Gielen, B. Mahieu, "Synthesis and characterisation of some new organotin(IV)tetraphenyldithioimidodiphosphinates", Main Group Metal Chem. 1993, 16, 435-443.

  2. C. Silvestru, R. Rösler, I. Haiduc, R. Cea-Olivares, G. Espinosa-Pérez, "Crystal and molecular structure of tetramethyldithioimidodiphosphinic acid, (SPMe2)2NH, and its cobalt(II) complex, Co[(SPMe2)2N]2, containing a tetrahedral CoS4 core", Inorg. Chem. 1995, 34, 3352-3354.

  3. R. Rösler, C. Silvestru, G. Espinosa-Pérez, I. Haiduc, R. Cea-Olivares, "Tetrahedral versus square-planar NiS4 core in solid-state bis(dithioimidodiphosphinato)nickel(II) chelates. Crystal and molecular structure of [Ni(SPR2)(SPR2)N]2, (R = Ph, Me)", Inorg. Chim. Acta 1996, 241, 47-54.

  4. R. Rösler, J. E. Drake, C. Silvestru, J. Yang, I. Haiduc, "The first crystal structures of mixed chalcogen derivatives SnR2[OPPh2)(SPPh2)N]2 (R = Me or Ph)", J. Chem. Soc., Dalton Trans. 1996, 391-399.

  5. C. Silvestru, R. Rösler, I. Haiduc, R. A. Toscano, D. B. Sowerby, "Dichlorodiphenylantimony(V) derivatives of oxo- and thioimidodiphosphinic acids, containing novel inorganic SbO2P2N and SbOSP2N rings: crystal and molecular structures of Ph2SbCl2[(OPPh2)(XPPh2)N] (X = O, S)", J. Organomet. Chem. 1996, 515, 131-138.

  6. A. Haaland, V. I. Sokolov, H. V. Volden, H. J. Breunig, M. Denker, R. Rösler, "The molecular structures and conformational preferences of bis(dimethylstibyl)-oxane, -sulfane and -selenane, E(SbMe2)2, E = O, S or Se, Me = CH3, by density functional theory calculations and gas electron diffraction", Z. Naturforsch. 1997, 52b, 296-300.

  7. H. J. Breunig, R. Rösler, E. Lork, "Sb8R4 , R = (Me3Si)2CH - A polycyclic organostibane", Angew. Chem. 1997, 109, 2333-2334; Angew. Chem. Int. Ed. Engl. 1997, 36, 2237-2238.

  8. H. J. Breunig, R. Rösler, "Organoantimony compounds with element-element bonds", Coord. Chem. Reviews 1997, 163, 33-53.

  9. A. Haaland, K.-G. Martinsen, M. A. Tafipolsky, H. V. Volden, R. Rösler, H. J. Breunig, "The molecular structure of dimethyltellurium dichloride by gas electron diffraction and ab initio calculations at the MP2 level", J. Mol. Structure 1997, 413-414, 301-305.

  10. J. Yang, J. E. Drake, S. Hernandez-Ortega, R. Rösler, C. Silvestru, "Crystal and molecular structures of (OPPh2)(SPPh2)NH and its sodium salt [Na{(OPPh2)(SPPh2)N}·2THF]2", Polyhedron 1997, 16, 4061-4071.

  11. H. J. Breunig, R. Rösler, E. Lork, "Complexes with Sb2- and cyclo-Sb3-ligands: the tetrahedranes [C5H5(CO)2Mo]2Sb2 , [C5H5(CO)2MoSb3] and [C5Me5(CO)2MoSb3]", Angew. Chem. 1997, 109, 2941-2942; Angew. Chem. Int. Ed. Engl. 1997, 36, 2819-282.

  12. C. Silvestru, J. E. Drake, R. Rösler, J. Yang, A. Silvestru, I. Haiduc, "Inorganic chelate (carbon-free) rings in monomeric and dimeric [RxM{(XPR’2)(YPR”2)N}y]n", Phosphorus, Sulfur, and Silicon 1997, 124 & 125, 63-72.

  13. R. Rösler, H. J. Breunig, E. Lork, "Complexes with cyclo-Sbn ligands", Phosphorus, Sulfur, and Silicon 1997, 124 & 125, 243-252.

  14. C. Silvestru, R. Rösler, J. E. Drake, J. Yang, G. Espinosa-Pérez, I. Haiduc, "Tetraorganodithioimidodiphosphinic acids and their neutral Co(II) complexes, containing stable tetrahedral CoS4 cores. Crystal structures of (SPMe2)(SPPh2)NH and Co[(SPMe2)(SPPh2)N]2", J. Chem. Soc., Dalton Trans. 1998, 73-78.

  15. A. Haaland, D. J. Shorokhov, H. V. Volden, H. J. Breunig, M. Denker, R. Rösler, "The molecular structures and conformational preferences of bis(dimethylstibyl)-sulfane and -tellurane, E(SbMe2)2, E = S or Te, Me = CH3, by density functional theory calculations and gas electron diffraction", Z. Naturforsch. 1998, 53b, 381-385.

  16. H. J. Breunig, R. Rösler, E. Lork, "The First Organobismuth Rings: (RBi)3 and (RBi)4, R = (Me3Si)2CH", Angew. Chem. 1998, 110, 3361-3363; Angew. Chem. Int. Ed. 1998, 37, 3175-3177.

  17. H. J. Breunig, R. Rösler, E. Lork, A Cyclotristibane: Synthesis and Crystal Structure of cyclo-[(Me3Si)2CH]3Sb3, Organometallics 1998, 17, 5594-5595.

  18. H. J. Breunig, M. Stanciu, R. Rösler, E. Lork, "Reaktionen von R4Sb2 (R = Me, Et) mit (Me3SiCH2)3M (M = Ga, In) und Kristallstrukturen von [(Me3SiCH2)2InSbMe2]3 und [(Me3SiCH2)2GaOSbEt2]2", Z. Anorg. Allg. Chem. 1998, 624, 1965-1968.

  19. R. Rösler, M. Stanciu, J. Yang, J. E. Drake, C. Silvestru, I. Haiduc, "New versatile organophosphorus ligands. Crystal and molecular structures of isomeric P,P-dimethyl-P’,P’-diphenyl-P-thioimidodiphosphinic and P,P-dimethyl-P,P-diphenyl-P’-thioimidodiphosphinic acids", Phosphorus, Sulfur, and Silicon 1998, 132, 231-250.

  20. A. Haaland, D. J. Shorokhov, V. I. Sokolov, H. V. Volden, H. J. Breunig, M. Denker, R. Rösler, "New aspects of the syntheses and molecular structures of Me2SbSeSbMe2 and related compounds", Phosphorus, Sulfur, and Silicon 1998 , 136, 137 & 138, 463-466.

  21. H. Althaus, H. J. Breunig, R. Rösler, E. Lork, "Synthesis and Characterization of R2BiCl and RBiCl2 [R = CH(SiMe3)2]", Organometallics 1999, 18, 328-331.

  22. H. Althaus, H. J. Breunig, J. Probst, R. Rösler and E. Lork, "The crystal structure of a trinuclear anion, [(t-Bu2Sb)2Sb]– formed by reaction of cyclo-(t-Bu4Sb4) with potassium, and the four membered rings, cyclo-(t-Bu4EnSb4-n) (E = P, n = 0 - 3; E = As; n = 0 - 2)", J. Organomet. Chem. 1999, 585, 285-289.

  23. H. J. Breunig, R. Rösler, E. Lork, "Syntheses and Crystal Structures of [(t-Bu4Sb4 )Fe(CO)4], [(t-Bu4Sb4)Mo(CO)5], and [(t-Bu3Sb4)Mo(h5-C5Me5)(CO)3]", Z. Anorg. Allg. Chem. 1999, 625, 1619-1623.

  24. Anca Silvestru, Hans J. Breunig, M. Stanciu, Roland Rösler, Enno Lork, "Synthesis and crystal structures of two trigonal bipyramidal Sb(V) compounds, R2SbBr3 and R3Sb(S2PPh2)2 (R = Me3SiCH2)", J. Organomet. Chem. 1999, 588, 256-259.

  25. Hans J. Breunig, M. Jönsson, Roland Rösler, Enno Lork, "Tetracarbonylchromkomplexe mit Me2SbESbMe2 (E = O, S) und MeSb(SSbMe2)2 als Liganden", Z. Anorg. Allg. Chem. 1999, 625, 2120-2124.

  26. Hans J. Breunig, Henrik Althaus, Roland Rösler, Enno Lork, "Novel Syntheses of Me2SbX (X = Cl, I) and Crystal Structures of Me2SbI and [(Me3Si)2CH]2SbCl", Z. Anorg. Allg. Chem. 2000, 626, 1137-1140.

  27. Anca Silvestru, Danut Bîlc, Roland Rösler, John E. Drake, Ionel Haiduc, "First nickel(II) complexes containing tetrahedral NiO2S2 cores. The molecular structures of Ni[(OPPh)(SPR2)N]2 (R = Ph, Me)", Inorg. Chim. Acta 2000, 305, 106-110.

  28. Hans J. Breunig, Enno Lork, Roland Rösler, Gerd Becker, O. Mundt, W. Schwarz, " Common features in the crystal structures of the compounds bis(dimethylstibanyl)oxane and -sulfane and the minerals Valentinite and Stibnite (Grauspießglanz)", Z. Anorg. Allg. Chem. 2000, 626, 1595-1607.

  29. Hans J. Breunig, M. Jönsson, Roland Rösler, Enno Lork, "Crystal structures of tris(trimethylsilyl)stibine and pentacarbonyl-(tris(trimethylsilyl)stibine)-chromium", J. Organomet. Chem. 2000, 608, 60-62.

  30. Hans J. Breunig and Roland Rösler, "New developments in the chemistry of organo antimony and bismuth rings", Chem. Soc. Reviews 2000, 29, 403-410 (invited).

  31. Hans J. Breunig, Neil Burford, and Roland Rösler, "Stabilization of a Pentastiba-Cyclopentadienyl Ligand in the Triple-Decker Sandwich Complexes [{(h5-1,2,4-tBu3C5H2)Mo}2(m,h5-Sb5)] and [(h5-1,2,4-tBu3C5H2)Mo(m,h5-Sb5)Mo(h5-1,4-tBu2-2-MeC5H2)]", Angew. Chem. 2000, 112, 4320-4322; Angew. Chem. Int. Ed. 2000, 39, 4148-4150.

  32. Anca Silvestru, Adina Rotar, John E. Drake, M. B. Hursthouse, M. E. Light, Sorin I. Farcas, Roland Rösler, Cristian Silvestru, "Synthesis, spectroscopic characterization, and structural studies of new Cu(I) and Cu(II) complexes containing organophosphorus ligands, and crystal structures of (Ph3P)2Cu[S2PMe2], (Ph3P)2Cu[(OPPh2)2N], Cu[(OPPh2)2N]2, and Cu[(OPPh2)(SPPh2)N]2", Can. J. Chem. 2001, 79, 983-991.

  33. Cristian Silvestru, Roland Rösler, Anca Silvestru and John E. Drake, "Solution and solid state structural investigations of organotin(IV) compounds containing asymmetric imidodiphosphinato ligands. X-ray structure of R"2Sn[(OPMe2)(OPPh2)N]2 (R = Me, Bun, Ph)", J. Organomet. Chem. 2002, 642, 71-79.

  34. Roland Roesler, Brian J. N. Har, and Warren. E. Piers, "Synthesis and characterization of (perfluoroaryl)borane-functionalized carbosilane dendrimers and their use as Lewis acid catalysts for the hydrosilation of acetophenone", Organometallics 2002, 21, 4300-4302.

  35. Michelle A. M. Forgeron, David L. Bryce, Roderick E. Wasylishen, and Roland Rösler, "A Solid-State Multinuclear Magnetic Resonance Investigation of Hexamethylborazine", J. Phys. Chem. A 2003, 107, 726-735.

  36. Roland Roesler, Warren E. Piers, and Masood Parvez, "Synthesis, structural characterization and reactivity of the amino borane 1-(NPh2)-2-[B(C6F5)2]C6H4", J. Organomet. Chem. 2003, 680, 218-222 (invited).

  37. Kelly E. Krahulic, Gary D. Enright, Masood Parvez, and Roland Roesler, "A Stable N-Heterocyclic Carbene with a Diboron Backbone", J. Am. Chem. Soc. 2005, 127, 4142-4143.

  38. Hanh V. Ly, Taryn D. Forster, Darren Maley, Masood Parvez and Roland Roesler, "µ-η3:η4-Lithiocene and η3:η3-Zincocene Incorporating 1,2-Diaza-3,5-diborolyl, a Cyclopentadienyl Analog", Chem. Commun. 2005, 4468-4470.

  39. Hanh V. Ly, Masood Parvez and Roland Roesler,"An Unusual Ligand in Copper Chemistry: Coordination Oligomers and Polymers containing the [{CpMo(CO)2}2(µ,η2-Sb2)] Cluster", Inorg. Chem. 2006, 45, 345-351.

  40. Taryn D. Forster, Kelly E. Krahulic, Heikki M. Tuononen, Robert McDonald, Masood Parvez, and Roland Roesler, "Anionic N-heterocyclic Carbene or Heterocyclic Terphenyl Anion? A σ-Donor with a Planar Six-π-Electron B2N2C2 Framework", Angew. Chem. 2006, 118, 6504-6507; Angew. Chem. Int. Ed. 2006, 45, 6356-6359.

  41. Hanh V. Ly, Taryn D. Forster, Andrea M. Corrente, Dana J. Eisler, Jari Konu, Masood Parvez, and Roland Roesler, "Alkali Metal Sandwich Complexes of a 1,2-Diaza-3,5-diborolyl ligand featuring η1, η2, η3 and η4 Coordination Modes", Organometallics 2007, 26, 1750-1756.

  42. Hanh V. Ly, Taryn D. Forster,  Masood Parvez, Robert McDonald, and Roland Roesler, "Zinc, Cadmium and Mercury Metallocenes Incorporating 1,2-Diaza-3,5-diborolyl ligands", Organometallics 2007, 26, 3516-3523.

  43. Hanh V. Ly, Heikki M. Tuononen, Masood Parvez, and Roland Roesler, "Assembly of a Planar, Tricyclic B4N8 Framework With s-Indacene Structure", Chem. Commun. 2007, 4522-4524.

  44. Hanh V. Ly, Joanna H. Chow, Masood Parvez, Robert McDonald, and Roland Roesler, "Revisiting the 1,2,4-Triaza-3,5-diborolyl Ligand: σ and π Coordination Modes in the Alkali Metal and Rhodium Complexes of a Planar, 6-π-Electron B2N3– Ring", Inorg. Chem. 2007, 46, 9303-9311.

  45. Heikki M. Tuononen, Roland Roesler,  Jason L. Dutton, and Paul J. Ragogna, "Electronic Structures of Main Group Carbene Analogues", Inorg. Chem. 2007, 46, 10693-10706.

  46. Hanh V. Ly, Heikki M. Tuononen, Masood Parvez, and Roland Roesler, "Unusual B4N2C2 Ligand in a Ruthenium Pseudo-Triple-Decker Sandwich Complex Displaying Three Reversible Electron Transfer Steps", Angew. Chem. 2008, 120, 367-370; Angew. Chem. Int. Ed. 2008, 47, 361-364.

  47. Anna Kausamo, Heikki M. Tuononen, Kelly E. Krahulic, Roland Roesler, "N-Heterocyclic Carbenes with Inorganic Backbones: Electronic Structures and Ligand Properties", Inorg. Chem. 2008, 47, 1145-1154.

  48. Hanh V. Ly, Jari Konu, Masood Parvez and Roland Roesler, "Tuning the electronic properties of cyclopentadienyl analogs with CB2N2 frameworks: 1,2-diphenyl-1,2-diaza-3,5-diborolyl ligands and their alkali metal salts", Dalton Trans. 2008, 3454-3460 (invited).

  49. Kelly E. Krahulic, Heikki M. Tuononen, Masood Parvez and Roland Roesler, "Isolation of Free Phenylide-like Carbanions with N-Heterocyclic Carbene Frameworks", J. Am. Chem. Soc. 2009,  131,  5858-5865.

  50. Taryn D. Forster, Heikki M. Tuononen, Masood Parvez, and Roland Roesler, "Characterization of β-B-Agostic Isomers in Zirconocene Amidoborane Complexes", J. Am. Chem. Soc. 2009,  131,  6689-6691. Editor's choice in Science, 2009, 324, 694.

  51. Matthew G. Hobbs, Taryn D. Forster, Javier Borau-Garcia, Chrissy J. Knapp, Heikki M. Tuononen and Roland Roesler, "The influence of electron delocalization upon the stability and structure of potential N-heterocyclic carbene precursors with 1,3-diaryl-imidazolidine-4,5-dione skeletons",  New J. Chem. 2010, 34, 1295-1308.

  52. Matthew G. Hobbs, Chrissy J. Knapp, Patrick T. Welsh, Javier Borau-Garcia, Tom Ziegler and Roland Roesler, "Anionic N-Heterocyclic Carbenes with N,N’-Bis(fluoroaryl) and N,N’-Bis(perfluoroaryl) Substituents", Chem. Eur. J. 2010, 16, 14520-14533.

  53. Hanh V. Ly, Jani Moilanen, Heikki M. Tuononen, Masood Parvez, and Roland Roesler, "More Electron Rich than Cyclopentadienyl: 1,2-Diaza-3,5-diborolyl as a Ligand in Ferrocene and Ruthenocene Analogs", Chem. Commun. 2011, in press.

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